Absorption 122
Actinoid contraction 231
Actinoids 209, 230
Activated complex 112
Activators 132
Activation energy 113
Adsorption 122
Adsorption isotherm 125
Allotropic forms 175, 187
Ambidentate ligand 240
Amorphous solids 2
Anisotropic 3
Anomalous behaviour of oxygen 182
Antiferromagnetism 28
Aqua regia 199
Arrhenius equation 111, 113
Atomic radii 166, 181, 193, 203
Average rate 95
Avogadro constant 20
Azeotrope 46, 47
Batteries 86
Binary solutions 33, 41, 44
Biochemical catalysis 131
Black phosphorus 176
Blast furnace 154, 156, 157
Blister copper 157
Body-centred unit 7, 11
Bohr magneton 27, 221
Bonding in metal carbonyls 254
Bravais lattices 7
Bredig's arc 137
Brown ring test 175
Brownian movement 140
Calcination 150, 154
Cast iron 156, 162
Catalyst 114, 128
Cell potential 66
Chelate 240
Chemical kinetics 93
Chemisorption 123
Chiral 245
Chromatographic methods 160
Cis - isomer 244, 245
Classification of colloids 134
Close-packed structures 12
Coagulation 142
Colligative properties 47, 56
Terms Page No.
INDEX
Terms Page No.
Collision frequency 115
Collision theory of chemical reactions 115
Column chromatography 161
Concentration of ores 149, 150
Concentration of solutions 34
Conductivity 73, 79
Conductors 24
Coordination compounds 237
Coordination entity 240, 242
Coordination isomerism 246
Coordination number 12
Coordination polyhedron 241
Coordination theory 239
Copper matte 151, 156
Corrosion 89
Cryoscopic constant 51
Crystal defects 22
Crystal field splitting 251, 252
Crystal field theory 247, 250
Crystal lattice 7
Crystalline solids 2, 3, 4
Dalton's law 41
Daniell cell 64
Denticity 240
Dependence on rate of concentration 98
Depressants 149
Dialyser 138
Dialysis 138
Diamagnetism 28, 220
Didentate 240
Diode 27
Dislocation defect 23
Dispersed phase 134, 135
Dispersion medium 134, 135
Dissociation constant 256
Distillation 159
Ebullioscopic constant 49
Electrical conductance 74
Electro dialysis 138
Electrochemical cells 64
Electrochemistry 63
Electrode potential 66, 218, 220
Electrolytes 79
Electrolytic cell 83
Electrolytic refining 159
Electromotive force 66
Electron hole 26
279 Index
Electron vacancy 26
Electronegativity 167, 181, 193
Electronic configuration 210
Electronic defect 26
Electroosmosis 142
Elements 147
Ellingham diagram 152
Eluant 161
Empirical formula 238
Emulsions 135, 143
Enantiomers 245
End-centred unit 8
Enthalpy 124
Enzyme catalysis 131, 132
Equilibrium constant 71
f.- block elements 227
Face centred unit 7, 11
Facial isomer 245
Faraday's law 83
Ferrimagnetism 28
Ferromagnetism 28, 221
First order reaction 104, 109
Froth floatation 149
Fractional distillation 169
Frenkel defect 22, 23
Frequency factor 111
Freundlich isotherm 125
Fuel cells 88
Galvanic cell 64, 65, 89
Gangue 147, 148
Gels 135
Geometric isomerism 244
Giant molecules 5
Gibbs energy 65, 72, 117
Haber's process 128
Half-life 108
Hall heroult process 158
Halogens 192
Henry's law 40
Heterogeneous catalysis 128, 129
Heteroleptic complex 241
Holme's signals 176
Homogeneous catalysis 128
Homoleptic complex 241, 254
Hybridisation 248
Hydrate isomerism 249
Hydration enthalpy 217
Hydraulic washing 148
Hydro metallurgy 158
Hydrogen bonded molecular solids 4
Ideal solution 45
Impurity defect 23
Inhibitors 132
Inner transition metals 209, 227
Instability constant 256
Instantaneous rate of a reaction 96, 97
Insulators 25
Inter molecular forces 2
Interstitial compounds 223
Interstitial defect 22
Intrinsic semiconductors 25
Ionic conductance 75
Ionic radii 166, 181, 193
Ionic solids 5
Ionisation enthalpy 166, 181, 193, 203
Ionisation isomerism 246
Isomerism 244
Isotonic solution 54
Kinetic energy 113
Kohlrausch law 81, 82
Kraft temperature 136
Lanthanide contraction 213, 228
Lanthanoids 209, 227
Le Chateliers principle 38
Leaching 150
Lewis acids 240
Ligand field theory 247
Ligands 222, 240
Line defects 22
Linkage isomerism 248
Liquation 161
Long range order 2
Lyophilic colloids 137
Lyophobic colloids 137
Magnetic separation 151
Meridional isomer 247
Metal carbonyls 256
Metal excess defect 23
Metallic solids 5
Metallurgy 149, 153
Micelles 138
Minerals 149
Mischmetall 232
Molal elevation constant 49
Molality 37
Molar conductivity 79
Molarity 36, 53
Mole fraction 35, 48
Terms Page No. Terms Page No.
Chemistry 280
Molecular orbital theory 249
Molecularity of a reaction 104
Mond process 162
Monoclinic sulphur 189
Mononuclear coordination compounds 244
Nernst equation 70
Noble gases 204
Non-ideal solution 45
Non-polar molecular solids 4
Octahedral voids 15, 17
Optical isomerism 245
Order of a reaction 100
Ores 148
Osmotic pressure 53
Ostwald's process 129
Oxidation number 241
Oxidation state 194
Oxides of nitrogen 172
Oxoacids of halogens 199
Oxoacids of phosphorus 178, 179
Oxoacids of sulphur 189
Ozone 185
Packing efficiency 18
Paper chromatography 161
Paramagnetism 27, 220
p-block elements 165
Peptization 138
Physisorption 123
Pig iron 156
Point defects 22
Polar molecular solids 4
Polydentate 240
Primary battery 86
Primary valence 237
Pseudo first order reaction 110
Pseudo solids 3
Purification of metal 147
Pyrometallurgy 151, 157
Raoult's law 41, 44
Rate law 98, 99
Reaction rate constant 99
Redox couples 65
Red phosphorus 175
Reverberatory furnace 151, 156
Reverse osmosis 55
Rhombic sulphur 187
Roasting 151, 154
Schottky defect 22, 23
Secondary battery 87
Secondary valence 237, 238
Semi conductors 25
Semipermeable membrane 53
Shape-selective catalysis 130
Short range order 2
Smoke screens 176
Solid state 2
Sols 135
Solubility 37
Solvate isomerism 247
Stereo isomerism 244
Stoichiometric defect 22
Strong field ligands 251
Structural isomerism 244
Super cooled liquids 3
Surface chemistry 121
Temperature dependence of rate 111
Tetrahedral permanganate 226
Tetrahedral voids 14, 16
Thermodynamics 154
Trans isomer 244
Transition metals 209, 212
Tyndall cone 139
Tyndall effect 139
Ultrafiltration 139
Unidentate 240
Unit cells 7, 10
Units of rate constant 101
Units of rate of a reaction 95
Vacancy defect 22
Valence bond theory 247, 250
Van arkel method 160
Vapour phase refining 160
Vapour pressure 42, 44
Voltaic cell 64
Weak field ligands 251
Werner's theory 237, 239
Wheatstone bridge 73, 75
White phosphorus 175
Wrought iron 156, 162
Zeolites 130, 131
Zero order Reaction 103, 109
Zeta potential 141
Zone refining 159, 160
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